Continued from page 1
As
peak height is related with carrier-gas rate, wide peaks eluted later will be much sharper. This allows a better identification of low concentrations (increase in analysis accuracy);
Attainment of symmetrical peaks also in case of nonlinear adsorption isotherm, as
rear of
band is at a higher pressure than
front;
The substantial enrichment,
increase in concentration of
component in
center of
band is conditioned by
compression of
band both as a consequence of
moving pressure gradient compared with
initial sorption pressure, and as a consequence of
presence of
moving gradient of
optimal linear speed accompanying
band of components being analyzed from
inlet to
outlet of
chromatographic column during
while analysis cycle (increase in
efficiency of
separation of
components);
The pressure of
gas in
column can be changed almost instantaneously and equilibrium can be attained in a very short time. Pressure re-regulation excludes
necessity of long "periods of cooling" of
column (express - analysis, economy of electricity), while temperature increase programming may either cause evaporation of
stationary phase, which "flies out" of
column, or destroy it chemically to various molecules, which also will soon come out by
carrier-gas. The repetitive cycles of heating and cooling may cause compression of solid support particles during expansion, followed by destruction (crumbling) during compression, which leads to a progressive change of permeability. The maximum possible effectivity of
chromatographic column - Hayrapetyan's Effect
The maximum possible effectivity of
chromatographic column - Hayrapetyan's E ff e c t
All
rest - XX century.
P. S.
C h r o m a b a r o g r a p h y A new step of effectivity, A first - hand new technology.
Toward
new century with a new technology.

ARAM HAYRAPETYAN 47/6 Vardanants Street, Vanadzor 377201, Republic of Armenia, E-mail: invent@freenet.am Web-site: HTTP://CHROMATOGRAPHY.HOTBOX.RU PUBLICATIONS AND ARTICLES: 57 published works, including 21 certificates for individual authorship from USSR and Russia, Germany, Czechoslovakia and Bulgaria. PERSONAL DATES: Born 17 May 1945, married, two children. Daughter born 1972, married. Son born 1977.